Wednesday, November 05, 2008
You deserved better, Saul
In September, this blog endorsed Saul Tigh and Laura Roslyn for president. Yesterday's defeat is the manifestation of the libelous rumours that the media has so industriously circulated. They have delivered our fleet right into the jaws of the Cylons. Perhaps the Lords have merely given us the leadership we deserve. In any case, I'm too upset to comment further.
Labels:
Battlestar Galactica,
Laura Roslin,
Saul Tigh,
tongue-in-cheek
Saturday, November 01, 2008
Friday, October 31, 2008
Dead man's party
Happy Halloween! When it came to choosing a costume this year, I considered many options. I could have been my evil, mirror-universe self, but I couldn't grow a goatee. I could also have been a mad scientist, but that wouldn't really be a costume. Ultimately I collaborated with Matt and we chose the best costumes ever: our boss.

The boss was a good sport about it. He didn't beat or fire us.
On a different note, I made up some mix tapes for Betty Jo to take to her sister's Halloween party. The totally sweet playlist follows.
Disc 1:
Disc 2:
Disc 3:

The boss was a good sport about it. He didn't beat or fire us.
On a different note, I made up some mix tapes for Betty Jo to take to her sister's Halloween party. The totally sweet playlist follows.
Disc 1:
| Track | Name | Artist |
| 1 | Dead Man's Party | Oingo Boingo |
| 2 | Cry Little Sister | Gerard McMann |
| 3 | People are Strange (Doors cover) | Echo and the Bunnymen |
| 4 | Bad Moon Rising | Creedence Clearwater Revival |
| 5 | The Devil Went Down to Georgia (Charlie Daniels Band cover) | Primus |
| 6 | Somebody's Watching Me | Rockwell |
| 7 | Ghostbusters | Ray Parker Jr. |
| 8 | Don't Fear the Reaper | Blue Öyster Cult |
| 9 | Hungry Like The Wolf | Duran Duran |
| 10 | Monster Mash | Misfits |
| 11 | Pet Sematary (Single Version) | The Ramones |
| 12 | Psycho Killer | Talking Heads |
| 13 | Devil Inside | INXS |
| 14 | Scary Monsters (And Super Creeps) | David Bowie |
| 15 | Superstition | Stevie Wonder |
| 16 | Tombstone Shadow | Creedence Clearwater Revival |
| 17 | Werewolves of London (Colour of Money) | Warren Zevon |
| 18 | Thriller | Michael Jackson |
Disc 2:
| Track | Name | Artist |
| 1 | This Is Halloween (Danny Elfman cover) | Marilyn Manson |
| 2 | Bad Things | Jace Everett |
| 3 | Lotion | Greenskeepers |
| 4 | Sympathy For The Devil | Guns N' Roses |
| 5 | Hell | Squirrel Nut Zippers |
| 6 | When You're Evil | Voltaire |
| 7 | Bark At The Moon | Ozzy Osbourne |
| 8 | Devil's Got a Holda Me | Colour |
| 9 | Highway To Hell | AC/DC |
| 10 | Murder By Numbers | The Police |
| 11 | Dead Fish on the Banks | The Goodnight Loving |
| 12 | Chase the Devil | Max Romeo |
| 13 | Pretend that we're dead | L7 |
| 14 | Possum Kingdom | Toadies |
| 15 | We Must Bury You | Katatonia |
| 16 | Only To Haunt You | The Von Bondies |
| 17 | Red Right Hand | Nick Cave And The Bad Seeds |
| 18 | Magic Dance | David Bowie |
Disc 3:
| Track | Name | Artist |
| 1 | Satan Is My Master | Ben Folds Five |
| 2 | Psycho Therapy | Skid Row |
| 3 | I Put A Spell On You | Creedence Clearwater Revival |
| 4 | The Boogie Monster | Gnarls Barkley |
| 5 | Living Dead Girl | Rob Zombie |
| 6 | Dracula | Gorillaz |
| 7 | Halloween | Dave Matthews Band |
| 8 | Hells Bells | AC/DC |
| 9 | Beetle-Snake | Danny Elfman |
| 10 | Soul Dracula | Hot Blood |
| 11 | Weird Science | Oingo Boingo |
| 12 | Satan Is My Motor | Cake |
| 13 | Taste Of Blood | Mazzy Star |
| 14 | Mary Anne | GWAR |
| 15 | Walking With A Ghost In Paris (Tegan & Sara vs. Mylo) | Party Ben |
| 16 | Abracadabr | Steve Miller Band |
| 17 | Black Magic Woman | Santana |
| 18 | Oogie Boogie's Song | Danny Elfman |
| 19 | Gonna Kill U | GWAR |
Saturday, October 18, 2008
Over the rainbow
I was in the lab yesterday drying and distilling some triethylamine for one of my projects. On a whim, I used a crystalizing dish full of copper shot instead of a heating mantle, oil bath, or sand bath. The resulting rainbow of copper brought a little joy into my day. Perhaps there is a lesson about grad school to be learned here... nah.

The rainbow resulted from the different rates of oxidation across the temperature gradient in the dish (~300 °C to 80 °C). There is a more thorough explanation for the phenomina in "Optical characterization of thin thermal oxide films on copper by ellipsometry" Derin, H.; Kantarli, K. Appl. Phys. A 2002, 75, 391–395, DOI: 10.1007/s003390100989

The rainbow resulted from the different rates of oxidation across the temperature gradient in the dish (~300 °C to 80 °C). There is a more thorough explanation for the phenomina in "Optical characterization of thin thermal oxide films on copper by ellipsometry" Derin, H.; Kantarli, K. Appl. Phys. A 2002, 75, 391–395, DOI: 10.1007/s003390100989
A copper oxide film grown thermally on a copper surface can be distinguished by the color of reflected light from the
copper oxide–copper film system. If the film grown on copper is cuprous oxide (Cu2O), the observed color changes from purple to blue, green, yellow and red depending on oxide thickness. However, cupric oxide (CuO) grown on a copper surface is black... The reflectance spectra in the visible region for the thick copper film and copper oxide–copper structures, for different oxide thicknesses, are shown in Fig. 8. The reflectance minimum that begins to show itself after the first oxidation time shifts towards long wavelengths as the thickness of oxide film increases. The observed colors of these samples changed from green to yellow for the oxide thicknesses given in Fig. 8. These colors arise from the reflectance drop passing a minimum at wavelengths between 4000 and 6000 Å in the reflectance spectrum of the Cu2O–Cu system. If the oxide films were CuO, the reflectance value would be zero for all wavelengths in the visible and therefore all samples of different oxide thickness would be black... The reflectance minima observed in Fig. 8 arise from the destructive interference of rays reflected from the air–copper oxide and copper oxide–copper interfaces.
Labels:
color,
copper,
lab,
rainbow,
serendipity
Saturday, October 11, 2008
Professional Development
You might be asking yourself, "Why haven't there been any new posts from that skeptical chemist?" Well, the answer is professional development. Every year, the Department of Chemistry hosts a recruiting event, Sponsors' Day, where the senior graduate students are invited to present posters and résumés for the consideration of invited recruiters. This year, Sponsors' Day lined up with the University's annual career fair. Between the two, the blog had to go on the back burner. Sorry.
The career fair was, as always, a cattle call. All of the employers were looking for engineers or undergrads and I got the feeling that I had educated myself out of the job market. In any case, the winner for coolest employer must have been the Aberdeen Proving Ground. During the description of their work, the recruiter said "blow up" at least four times while standing in front of a video of stuff blowing up. How awesome is that?
Sponsors' Day consisted of me standing next to my poster for three hours while trying to avoid blinding sunlight. The only people that stopped to hear my spiel were two recruiters that had already signed up to interview me. I wondered if I could have saved myself the trouble of making a poster and slept in that day. In the end, it all went pretty well. Nobody noticed that I had written "Colymerization" in my poster title, and I got five screening interviews with some good employers.
The dark horse employer was VWR, which was recruiting PhDs for management and sales positions. I'll admit that the thought of giving up research has occurred to me (and pretty much every PhD candidate that I know), but I'm not sure that I want to give up all this fame and fortune just yet. Seriously though, I imagine that getting back into research or academics would be difficult after a couple of years if I decided that I didn't like management.
The career fair was, as always, a cattle call. All of the employers were looking for engineers or undergrads and I got the feeling that I had educated myself out of the job market. In any case, the winner for coolest employer must have been the Aberdeen Proving Ground. During the description of their work, the recruiter said "blow up" at least four times while standing in front of a video of stuff blowing up. How awesome is that?
Sponsors' Day consisted of me standing next to my poster for three hours while trying to avoid blinding sunlight. The only people that stopped to hear my spiel were two recruiters that had already signed up to interview me. I wondered if I could have saved myself the trouble of making a poster and slept in that day. In the end, it all went pretty well. Nobody noticed that I had written "Colymerization" in my poster title, and I got five screening interviews with some good employers.
The dark horse employer was VWR, which was recruiting PhDs for management and sales positions. I'll admit that the thought of giving up research has occurred to me (and pretty much every PhD candidate that I know), but I'm not sure that I want to give up all this fame and fortune just yet. Seriously though, I imagine that getting back into research or academics would be difficult after a couple of years if I decided that I didn't like management.
Labels:
career,
poster,
Sponsor's Day
Thursday, September 04, 2008
Chipmunks' Labor Day Special
While on my way to the Berkey Creamery with Eden, Lisa, and Richard on Monday, we came across a baby chipmunk on the sidewalk. Thinking it was lost, I put it back in the bushes for its mother to find. Unfortunately, we found two more right around the corner, one of which had an open wound. They were old enough that they had their fur and were able to scoot around on the sidewalk, but their eyes weren't open enough to see where they were going. They had all the elements of cuteness: fuzzy, helpless, and tiny with baby proportions! We concluded that their mother had died and they had been driven out by thirst so we gathered them up in my hat and took them to Centre Wildlife Care. My hopes aren't high for the injured one, but I'm sure Robyn and her crew will do their best.

UPDATE:
Richard spoke with Robyn and she said that two of the chipmunks died the first day and the third died unexpectedly a few days later. She said that was surprising since they had good luck with baby chipmunks in the past. So it goes.

Three orphaned chipmunks in my hat. The wounded one is in the upper-right.
UPDATE:
Richard spoke with Robyn and she said that two of the chipmunks died the first day and the third died unexpectedly a few days later. She said that was surprising since they had good luck with baby chipmunks in the past. So it goes.
Labels:
Berkey Creamery,
Centre Wildlife Care,
chipmunks,
cute,
Eden,
hat,
Lisa,
Richard,
Robyn Graboski,
so it goes
Wednesday, September 03, 2008
Tigh for president
Now that the presidential candidates for the Democratic and Republican parties have been finalized, I would like to take a moment to officially announce The Skeptical Chemist's endorsement of a candidate: Saul Tigh.

Looking at the tough issues that face our nation, I feel that Tigh's experience as a veteran of the Cylon war and leader of the fleet makes him the most qualified candidate. I'm confident that the people will agree and elect Tigh in spite of the main-stream media's libelous attempts to assassinate his character by suggesting that he might be a secret Cylon.

Looking at the tough issues that face our nation, I feel that Tigh's experience as a veteran of the Cylon war and leader of the fleet makes him the most qualified candidate. I'm confident that the people will agree and elect Tigh in spite of the main-stream media's libelous attempts to assassinate his character by suggesting that he might be a secret Cylon.
Labels:
Battlestar Galactica,
Laura Roslin,
Saul Tigh,
tongue-in-cheek
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